What is the molar ratio of EDTA to CaCO3?
0.001 L x 0.02 equivalent EDTA/L = 0.00002 equivalent EDTA = equivalent CaCO3. Each mL EDTA used = 0.00001 moles CaCO3:0.001 L x 0.01 mol EDTA/L = 0.00001 moles EDTA = moles Ca or CaCO3.
How do you standardize EDTA solution with CaCO3?
0.01M EDTA standardization against calcium carbonate
- Weight exactly about 1g of dry calcium carbonate.
- Dissolve solid in 25 mL of 1M HCl solution and dilute in volumetric flask to exactly 1L.
- Transfer 25 mL of calcium solution to Erlenmeyer flask.
- Add 75 mL of distilled water.
- Add 10 mL of 1M sodium hydroxide solution.
How many moles of EDTA react with Ca2+?
One mole
One mole of Ca2+ ions will react with one mole of EDTA ions. The complex is particularly stable and its formation takes place in a controlled 1:1 ratio, according to Equation 1).
What is the indicator for EDTA titration against CaCO3?
The method uses a very large molecule called EDTA which forms a complex with calcium ions. EDTA stands for ethylenediaminetetraacetic acid. A blue dye called Patton and Reeder’s indicator (PR) is used as the indicator.
How do you find the ppm of CaCO3?
The formula to convert an ion reported as “mg/l as the ion” to “ppm as calcium carbonate” is to multiply “mg/l as the ion” times the ratio of the “equivalent weight of the ion” by the “equivalent weight of calcium carbonate”.
What is the molarity of CaCO3?
The molarity of a calcium carbonate (molar mass = 100. g/mol) solution is 2.4 x 10 ^-3 .
How do you find the chemical equivalent of CaCO3?
Answer: Equivalent mass of Ca in CaCO3 = 50g. Explanation: The equivalent mass of CaCO3 is 100g/2=50g.
What is Eriochrome Black T indicator?
Eriochrome® Black T is used as an indicator for complexometric titrations. It functions as an acid-base indicator. Eriochrome® Black T forms complex with Ca2+ and Mg2+, but it binds more strongly to Mg2+ ions. Eriochrome® Black T is a hydroxyl-arylazo dye and is generally supplied as a monosodium salt.
What is the molarity of Ca2+?
AS the name says on the tin, the molarity of calcium ion is 2.5⋅mol⋅L−1 ….
How does EDTA complex with Ca2+ and Mg2+?
The indicator is added and remains blue as all the Ca2+ and Mg2+ ions present are complexed with the EDTA. A back titration is carried out using a solution of magnesium chloride. This forms a complex with the excess EDTA molecules until the end-point, when all the excess EDTA has been complexed.
How many milliliters of EDTA are needed to titrate the Ca?
25.00 mL aliquot from above example is titrated with EDTA. 32.83 mL of EDTA was required.
What is eriochrome black T indicator?
Why is the titration of Ca +2 with EDTA-4 stable?
It derives its stability in part to calcium being connected to the EDTA by six bonds. In the titration of Ca +2 with EDTA -4 to produce CaEDTA -2, all components are colorless so you can not tell when you have added the stoichiometric amount of EDTA to the reaction.
How do you dissolve calcium carbonate in EDTA?
Pure Calcium Carbonate is dissolved by adding a slight excess of HCl. This solution is then quantitatively transferred to a 100 mL volumetric flask, diluted to volume and mixed thoroughly. This standard calcium solution, of known concentration, is used to determine the exact concentration of the EDTA solution.
How do you calculate the moles of EDTA in hard water titration?
The calculation is rather trivial moles of EDTA used = moles of Ca2+ (as calcium forms 1:1 complex with EDTA) = moles of CaCO3 and even = moles of Ca (HCO3)2. One can easily convert moles of CaCO3 into parts per million from the known volume of hard water taken from titration.
How is the concentration of EDTA determined?
This solution is then quantitatively transferred to a 100 mL volumetric flask, diluted to volume and mixed thoroughly. This standard calcium solution, of known concentration, is used to determine the exact concentration of the EDTA solution.